This programme is dedicated to studying iodine chemistry under thermal non equilibrium (impact of chemical kinetics) in the primary cooling system in the event of a core meltdown accident in a water reactor.

The CHIP programme follows two axes which respectivly aims to:

• Identify physico-chemical elements which may have a reaction with iodine during his transfert from core to containment structure (short transfert duration, fast cooling...) and also identify chemical species which influence presence of volatile iodine;
• Get kinetics datas of the main reactions.

So as to fulfill these objectives, the experimental programme uses more or less complex "phenomenolgy" lines in the form of experimental facilities and a "analytical" line.



The data collected will be used to validate the transport models for iodine in the primary cooling system, which are integrated in the ASTEC software. This software is developed by the DPAM to predict the different types of possible accidents and the related radioactive product releases.



The CHIP programme is run by IRSN/DPAM and is part of the International Source Term Programme co-funded by the CEA, EDF, IRSN, the European Commission, the US Nuclear Regulatory Commission (NRC), the Atomic Energy of Canada Limited (AECL), the Korea Institute of Nuclear Safety the Paul Scherrer Institute and SUEZ-Tractebel over the 2005-2012 period.

Facility is in operation.

Since the core meltdown accident in the Three Mile Island reactor in 1979, a series of experimental safety research programmes has been conducted by a number of international research organisations, including the IRSN, which manages the European SARNET network. Simulation models have been developed to calculate the sequence of events in an accident of this type, evaluate its consequences and assess the efficacy of the various measures that can be implemented to limit its effects.



The PHEBUS FP research programme was launched in 1988 by the IRSN (under the former name IPSN – Institut de Protection et de Sûreté Nucléaire, Nuclear Protection and Safety Institute) in partnership with the European Commission and EDF. France collaborated in this programme with the United States, Canada, Japan, South Korea and Switzerland, and five experiments were conducted between 1993 and 2004, involving approximately 80 persons per year.



The main objective was to reduce the uncertainty in evaluating the release of radioactive products in the event of a core meltdown accident in a pressurised water reactor (PWR). To do this, “global” experiments were conducted, that is, experiments in which all the phenomena were represented, from melting of a fuel assembly to release of fission products and structural materials inside a simulated containment vessel, duplicating as closely as possible the conditions that would apply in an accident of this type. The programme had the simultaneous aim of developing and validating the simulation software used to calculate the progression of the accident. This research was to contribute to improving IRSN crisis management by optimising the activities and procedures that would be implemented in the event of a nuclear accident to protect the population and the environment.

Facility is dismanteled.

The first tests were the HEVA series conducted between 1983 and 1989 where, with maximum temperatures restricted to 2100K, the main objective was to generate information on release of volatile FPs from UO2 fuel. Between 1989 and 1996, the tests VERCORS 1 to 6 were conducted with an improved apparatus and fuel temperatures up to 2600K, i.e., higher than those in HEVA so as to expand assessment of release to lower volatility FPs and begin to address issues of UO2 fuel degradation. The apparatus also allowed, to a limited extent, investigation of FP transport.



Between 1996 and 2002, the test series VERCORS HT and RT were performed where the main intention was to improve the database with respect to transport aspects and FP release during later accident phases, i.e., encompassing highly-degraded fuel states (debris, liquefaction). The effect of other parameters on FP release was also studied, notably the influence of high fuel burn-up (up to 70GWd/tU) and mixed-oxide fuel (MOX). The particularity of the RT series was the simplification of the apparatus downstream of the crucible allowing better quantification of low-level releases. Eight RT tests were performed in a variety of atmospheres, namely pure hydrogen, steam-hydrogen mixtures and one test with a helium-air mixture. The particularity of the HT tests was that they included a well-characterized transport system downstream of the crucible allowing deposition and sampling measurements to be made. This series comprised three complementary tests covering the full range of H2-H2O atmospheres with and without the presence of control-rod elements (Ag-In-Cd-B) in order to assess their effect on FP retention.



All six VERCORS tests, most of the VERCORS RT tests and all three HT tests included low- power re-irradiation of the fuel sample in an experimental reactor for a week to re-create the short half-life FP inventory. This allowed the measurement of lower volatility FPs to be considerably enriched. Furthermore, all except three of these tests were conducted with an intermediate temperature plateau (1500K or 1800K) lasting one hour such that full oxidation of the cladding occurred and early sample liquefaction was precluded.



IRSN has for some time been using its computer codes to analyse the results of the VERCORS tests. These codes are the mechanistic release code MFPR [2,3], the simplified release code ELSA [4] (a module of the integral code ASTEC [5]) and the transport code SOPHAEROS [6] (also a module of ASTEC). Regarding the study of FP release, the focus of this work has been on VERCORS 4 and 5 as well as some of the RT tests. In particular, the detailed interpretation made possible with the MFPR code is shedding light on how the oxidation state of the fuel affects the FP chemistry modifying the different fuel phases. Most notably, it is currently thought that the FP Mo, often considered a main component of metallic inclusions during reactor operations, acts to a certain extent as an oxygen buffer (by forming MoO2) with respect to other FPs, i.e., playing a key regulatory role in the chemical forms of the FPs, especially Cs, and hence their volatility and release [7]. With respect to FP transport, the HT tests represent the major interest. Currently, full results of the HT1 test have been available for some time; those of HT3 have just recently been finalized while HT2 was performed in 2002 and results are still awaited. Hence, interpretation of the transport results is, as yet, preliminary [8]. In general terms, it is seen that the usual release categories of volatile, semi-volatile and low volatility FPs can be quite misleading during transport since behaviour can change radically as a function of the in-fuel and ex-fuel differences. One particular point of interest concerns the distinctive difference in behaviour between caesium and iodine where iodine seems to exhibit volatile behaviour whatever the conditions while Cs tends towards different levels of intermediate volatility depending on the reactive species present (molybdenum, boron, etc.). Another aspect being investigated is the conditions leading to significant deposition of so-called semi-volatile FPs (Ba, Mo, Ru, etc.) close to their point of release.

Facility is dismanteled, replaced by VERDON.

No description available.

VERDON programme has been launched by the CEA as a follow-up of VERCORS programme. It addresses the consequences of a degradation of fuel elements in contact with air following penetration of the vessel after the meltdown of part of the reactor core or the dewatering of a spent fuel storage pit, especially the release and chemical behaviour of ruthenium (tests of release of fission products have been held under EPICUR programme as well).

The data base on Ru release under air ingress conditions from irradiated PWR fuel rods was still scarce, as in the VERCORS programme, few tests have been performed in very oxidising conditions and more particularly under air ingress with significant amount of air. In this context, VERDON programme included specific air ingress test on a genuine irradiated UO2 fuel sample in its original cladding. As in VERCORS programme, the sample has been previously reirradiated at low power in a MTR reactor, in order to rebuild the inventory of short halflife fission products (including 103Ru). This test has been conducted in a new dedicated hot cell. The aim was not only to measure the release of fission products, but also to study their deposit on thermal gradient tubes and their potential revolatilisation induced by air injection. Compared to VERCORS, VERDON included by more detailed examinations of the fuel sample before and after the tests, using microanalytical techniques, such as SEM, EPMA and SIMS in order to determine the location of the fission products within the various phases as well as the corresponding compounds if possible. This gave better understanding of the mechanisms, which promote fission products release in such situations, as well as supported the associated modelling. VERDON programme is a part of the International Source Term Programme, which is composed of separate effect tests aiming at reducing uncertainties in severe accident analyses.
Facility is in operation.

Complex measurements were performed at the integral high temperature test facility CODEX (COre Degradation Experiment) between 1995-2002 with electrically heated UO2 fuel rod bundles. The test matrix included the first VVER-440 type integral severe accident experiment. The results of a quench test with pre-oxidised bundle indicated the protective role of the external oxide scale. Unique experiments were performed with PWR bundles under air ingress conditions. The last test of the current series helped to resolve the methane production issue during the oxidaton of a boron-carbide control rod in a severe accident. Some experiments were related to the preparation of PHEBUS tests, and some others were performed parallel with similar QUENCH tests. The experimental results contributed to the general understanding of severe accident progression in the loss of rod-like geometry phase and the test data have been used and are available for model development and code validation purposes.

The CODEX out-of-pile integral test facility was built and put into operation in 1995 at the KFKI Atomic Energy Research Institute, Hungary in order to investigate some specific aspects of core degradation and to extend the experimental database for code valiadation and development. Some of the experiments were VVER specific, while others were of general interest for any light water reactor. The comparison of CODEX exepriments with CORA and QUENCH tests can help to sift out the effects related to the specific features or scaling of the facilities. Some new techniques (e.g. aerosol measurements) applied in the test facility provide additional information on the high temperature behaviour of core materials. For the investigation of the aerosol release a cascade impactor system is connected to the upper plenum of the cooler and two pipelines allowes the continuous measurement of aerosols by means of laser particle counters. The gas concentration in the off-gas system is measured using a quadropole mass spectrometer. The instrumentation of the facility consists of the measurements of the operational parameters as heating power, flowrates, temperatures, levels and pressures. Thermocouples are placed in several positions in the heat insulation material, on the heat shield, on the external surface of the shroud, on the fuel rods and inside of the central (unheated) rod. Two pyrometers and a video camera are located at three windows in the upper part of the bundle. After the experiments the post-test examination of the bundle and aerosol samples is carried out with several techniques, including metallography, SEM, microprobe analysis, X-ray radiography and mass spectrometry.
Facility is not in operation.